You cannot put out a gasoline, solvent or jet-fuel fire with plain water. The water sinks below the hydrocarbon and the flame carries on at the fuel surface. That is why refineries, hangars and fuel depots use foam-water sprinkler systems: under NFPA 16, foam concentrate is proportioned into the water and discharged through the sprinklers. The foam spreads over the fuel like a blanket and cuts off oxygen. This post explains the basic logic of foam-water design in field terms.
Why Foam?
Three physical facts define a hydrocarbon fire:
- Fuel is lighter than water — water sinks straight below it.
- Burning happens at the fuel surface — the top of the flame zone must be covered.
- Vapor can re-ignite even after extinguishment — re-ignition must be prevented.
Foam solves all three in one move: it blankets the surface, traps the vapor and cuts off oxygen.
Foam Types
- AFFF (Aqueous Film-Forming Foam): the most common type, proportioned at 3% or 6%; the standard choice for hydrocarbons such as gasoline, diesel and kerosene.
- AR-AFFF (Alcohol Resistant AFFF): for polar solvents such as alcohol and acetone; designated 3%×3 or 3%×6.
- Protein foam: the classic type; usually preferred for tank rim-seal applications.
- Fluorine-free foam (F3): the new generation after the PFAS ban; performance is a step or two behind AFFF, but development is moving fast.
Proportioners
Equipment that mixes foam concentrate into water at the correct ratio:
- Bladder tank: works on system water pressure and delivers foam to the line within minutes; the most common solution on site.
- Balanced pressure pump: a separate pump injects the concentrate; suited to large systems.
- Around-the-pump: concentrate injected into a side stream of the main pump; preferred for mid-size systems.
- Inline eductor: useful for small installations; high pressure loss.
Application Rates
The NFPA 16 application rates we use most in practice:
- Hydrocarbon sprinkler: 0.10-0.16 gpm/ft² (4.1-6.5 mm/min) foam solution × 10 min
- Aircraft hangar: 0.16 gpm/ft² (6.5 mm/min) × 10 min (NFPA 409)
- Deluge foam system: 0.20 gpm/ft² (8.1 mm/min) × 10 min
When the foam period ends, the system switches to plain water and the cooldown phase begins. Accounting for both phases separately is critical for concentrate stock and tank volume.
Test and Maintenance
- Annual foam concentrate quality test (chloride, pH, refractive index)
- Proportioner flow test every 3 years
- Discharge test every 10 years (costly; environmental concern)
- After the PFAS ban, legacy concentrate stocks are special waste and cannot be disposed of by normal routes
The PFAS Transition
In 2024 AFFF was banned in Europe because of its PFAS content. Turkey has no active ban yet, but the transition has quietly started. Three jobs await legacy systems:
- Conversion to F3 (fluorine-free) concentrate
- Safe disposal of legacy concentrate — no burning on site; a specialized high-temperature facility is required
- Equipment cleaning: even PFAS residue on valve and pipe interiors is a problem
Conclusion
Foam-water sprinklers are the main tool of hydrocarbon fire engineering; sprinklers, proportioner, concentrate and pump only make sense working as a team. The PFAS transition is reshaping the industry — F3 conversion takes serious investment but has become an environmental necessity. Major hangar and refinery owners in Turkey have long since put it on the planning table.

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Download SprinkCalc on the App StoreCore references: NFPA 16, NFPA 11, NFPA 409. Original NFPA post: NFPA Today - Foam Water.