A flammable liquid fire is not afraid of water; throw water on it and the flame spreads, and the fire area grows. Annex G makes sprinklers plus AFFF foam plus bunding mandatory for flammable liquid storage. The Class I/II/III split and the flash point are the foundation of the design.

A chemical supplier's warehouse held 80 IBCs of acetone — flash point −20 °C, Class IA — under standard OH3 water-only sprinklers. One IBC ignited from a static spark. The sprinklers operated, water fell onto the acetone, and since acetone floats it burned on the surface and spread the fire to 600 m² within four minutes. The water then carried acetone leaking from the IBCs across the floor and, with no bund in place, out under the door onto the road. Annex G is explicit: Class I means AFFF foam, bunding and limited stock. Sprinklers alone are not a design.

Flammable liquid classification

ClassFlash point (°C)Typical productSprinkler strategy
IA< 23 (boiling < 38)Ether, propylene oxideAFFF, bund and monitors
IB< 23 (boiling ≥ 38)Acetone, petrol, ethanolAFFF foam-water
IC23–38Thinners, xyleneAFFF foam-water
II38–60Diesel, kerosene, paraffinAFFF or high-density water
IIIA60–93Motor oil, fuel oilHigh-density water (CMDA)
IIIB> 93Vegetable oilWater (HHS)

Design densities

ClassWater densityFoam proportionAreaDuration
IA–IB10 mm/min3 % AFFF or 1 % fluorine-free260 m²60 min
IC–II8 mm/min3 % AFFF260 m²60 min
IIIA10 mm/minCase by case260 m²90 min
IIIB7.5 mm/minNone260 m²90 min

The foam-water sprinkler system

The sprinkler discharges water pre-mixed with AFFF concentrate; the foam blankets the liquid surface and cuts off oxygen. The components:

IBC and drum stacking rules

The bund

Bund capacity is 110 % of the largest single container plus 30 min of sprinkler discharge over the design area. For example, one 1000 L IBC gives 1100 L at 110 %; sprinklers at 10 mm/min over 260 m² for 30 min add 78 000 L. That gives a 79.1 m³ bund. In practice 25 % of total stock is accepted as the alternative basis, and the larger of the two governs.

The move away from PFAS foams

Traditional C8 AFFF contains PFAS and is being restricted across the EU between 2025 and 2030 under REACH. EN 12845 accepts fluorine-free (F3) foams. The migration sequence:

Field error — machine oil treated as OH3

A textile machinery parts warehouse stored lubricating oil with a 95 °C flash point (Class IIIA) in 200 L drums. The designer proposed OH3 at 5 mm/min on the assumption that oil is harmless. The insurer's audit recorded that Annex G requires 10 mm/min over 90 min for Class IIIA — a doubling of density. Even Class III liquids demand a high water density, because once a fire takes hold the oil mass reaches 700–900 °C and many sprinklers operate. The rule that flammable liquid means high density is unconditional.

Monitors and large-fire protection

Above 50 000 L of stock, sprinklers alone are not sufficient and perimeter monitors are added:

Comparison with NFPA 30 and FM Global

NFPA 30, the Flammable and Combustible Liquids Code, is the comprehensive counterpart to Annex G. NFPA limits Class IA and IB to a single tier (1.8 m) where Annex G accepts two. FM Global's data sheet on flammable liquid storage in portable containers gives detailed stack geometry, bunding and foam design. Refining and petrochemical facilities in Turkey work to NFPA 30 with the FM data sheet, while Annex G is sufficient for a smaller chemical supplier.

Turkish regulation and local practice

BYKHY devotes several clauses to flammable liquid storage, covering stock limits, bunding, ventilation and ATEX zoning, and directs sprinkler design to Annex G or NFPA 30. The Seveso III framework requires a risk assessment for stocks above 50 000 L. Annex G is the working fire protection standard in Turkey's chemical industrial zones.

Quick check list

Frequently Asked Questions

Why can water make a flammable liquid fire worse?

Because most flammable liquids float on water. Sprinkler water spreads burning liquid across the floor rather than cooling it, which is why a foam blanket is essential for Class I and II.

How is the bund sized?

110 % of the largest single container plus 30 min of sprinkler discharge over the design area — or 25 % of total stock, whichever is greater.

How high can IBCs and drums be stacked?

Two tiers for 1000 L plastic IBCs and three tiers for 200 L steel drums, roughly 3.6 m in both cases, with 1.2 m aisles between stacks.

What is changing with AFFF?

PFAS-containing C8 foams are being restricted across the EU between 2025 and 2030 under REACH. Migration to certified fluorine-free F3 foam requires tank cleaning, re-proportioning and a functional retest.

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Standards & References

BS EN 12845:2015+A1:2019 Fixed firefighting systems — Automatic sprinkler systems. EN 12845-2:2024 (CMSA & ESFR sprinkler systems). NFPA 13 Standard for the Installation of Sprinkler Systems. Turkish Regulation on Fire Protection of Buildings (BYKHY). FM Global Property Loss Prevention Data Sheet 2-0.

FS

Fatih Selvi

Mechanical engineer and software developer with field experience in MEP and fire protection, working actively with NFPA, FM Global and BS EN 12845 on site projects.